TITLE: Double modules', double categories and groupoids, and a new homotopical double groupoid AUTHOR: Ronald Brown ABSTRACT: We give a rather general construction of double categories and so, under further conditions, double groupoids, from a structure we call a `double module'. We also give a homotopical construction of a double groupoid from a triad consisting of a space, two subspaces, and a set of base points, under a condition which also implies that this double groupoid contains two second relative homotopy groups. AUTHOR'S ADDRESS: School of Computer Science, Bangor University, Bangor, Gwynedd, LL57 1UT, UK web site: www.bangor.ac.uk/r.brown AMSCLASSIFICATIO: 18B40,18D05,55E30 KEYWORDS: double categories, double groupoids, crossed modules, second relative homotopy groups arXiv: 0903.2627